In 1939, Martin Kamen and Samuel Ruben of the Radiation Laboratory at Berkeley began experiments to determine if any of the elements common in organic matter had isotopes with half-lives long enough to be of value in biomedical research.They synthesized Libby and several collaborators proceeded to experiment with methane collected from sewage works in Baltimore, and after isotopically enriching their samples they were able to demonstrate that they contained radioactive .
The results were summarized in a paper in Science in 1947, in which the authors commented that their results implied it would be possible to date materials containing carbon of organic origin.
Research has been ongoing since the 1960s to determine what the proportion of in the atmosphere has been over the past fifty thousand years.
The resulting data, in the form of a calibration curve, is now used to convert a given measurement of radiocarbon in a sample into an estimate of the sample's calendar age.
Animals eat the plants, and ultimately the radiocarbon is distributed throughout the biosphere.
The ratio of λ is a constant that depends on the particular isotope; for a given isotope it is equal to the reciprocal of the mean-life – i.e.